聚丙烯基高分子功能材料吸附卷烟烟气中多种有害成分的应用Application of a polypropylene function material to simultaneous reduction of the various detrimental components in cigarette smoking
胡秀峰;康晓鸥;霍晓晖;王玉林;何爱民;李占臣;韦丽红;路达;梅博;
摘要(Abstract):
为了寻找能同时降低卷烟烟气中甲醛、乙醛、巴豆醛和颗粒物有害成分含量的离子交换树脂吸附材料,采用电镜扫描方法观察聚丙烯基阳离子树脂高分子功能材料的表面特征,应用压汞法分析其平均孔径、中值孔径、比孔容和比表面积,并测试了该材料的交换容量,采用环境试验舱检测法对比测试了该材料和活性炭降低卷烟烟气中甲醛、乙醛、巴豆醛和颗粒物有害成分含量的效果。结果表明,聚丙烯基高分子功能材料表面多斑点状突起,凹凸状明显,微孔和缝隙多,平均孔径为0.26μm,中值孔径为149.3μm,比孔容为19.23 cm3/g,比表面积为293.42 m2/g,交换容量为5.16 mmol/g,对烟气中甲醛、乙醛、巴豆醛和颗粒物的净化率分别达到79.6%、79.8%、82.8%和64.7%,而活性炭的净化率分别为20.3%、0、6.4%和54.2%。研究表明,该聚丙烯基高分子功能材料具有物理吸附和化学吸附性能,净化卷烟烟气中多种有害成分的效果明显优于活性炭。
关键词(KeyWords): 环境工程学;烟气净化;卷烟烟气;聚丙烯基高分子功能材料;有害成分;活性炭
基金项目(Foundation): 科技部创新基金项目(11C26211100052)
作者(Authors): 胡秀峰;康晓鸥;霍晓晖;王玉林;何爱民;李占臣;韦丽红;路达;梅博;
参考文献(References):
- [1]CHENG Shenggao(程胜高),LIU Zhuo(刘卓),HUANG Fan(黄凡),et al.Smoke effects of indoor air and their control countermeasures[J].Environmental Protection(环境保护),2002(4):30-31.
- [2]HUO Xiaohui(霍晓晖),WANG Yulin(王玉林),HU Xiufeng(胡秀峰),et al.The filtration effect of the cigarette filters made of different fiber filtrational materials in reducing tar and other harmful components[J].Science&Technology Review(科技导报),2007,25(22):76-80.
- [3]MA Jianbiao(马建标),LI Chenxi(李晨曦).Functional polymer(功能高分子材料)[M].Beijing:Chemical Industry Press,2000.
- [4]CROOKS E L,CASH S L,TAYLOR J N,et al.Filtered cigarette has semi-permeable barrier that divides compartment into primary and secondary regions,to place adsorbent material in primary region and ion exchange resin in secondary region:US,US2005066984-A1[P].2005-03-21.
- [5]ZAWADZKI M A,RUDD A B,BARETT K D,et al.Tobacco cigarette comprises filter including adsorbent for gas phase constituent of mainstream smoke and off-taste suppressant:US,US2004231684-A1[P].2004-11-25.
- [6]FIGLAR J N,TUCKER B E,ST CHARLES F K,et al.Multiple section cigarette filter comprising selective adsorbent material with affinity for chemical compounds dispersed throughout fibrous material,and general adsorbent material:US,US2003066539-A1[P].2004-12-02.
- [7]YOSHIKAWA S,YOSHIOKA T,SHIMAMURE M.Tobacco smoke filters based on fibrous ion exchange resins—for removal of polar and ionic substances,also nicotine substances:US,US4700723-A[P].1987-10-20.
- [8]FISHER B.Advances in safer smokes[J].Tobacco Reporter,2001(11):22-24.
- [9]HU Xiufeng(胡秀峰),ZHOU Shaoji(周绍箕),HU Lili(胡丽丽),et al.A method of preparing a new shape polypropylene function material(一种菜花状高分子功能材料制备方法):China,ZL201010173537.x[P].2011-03-16.
- [10]YAN Guoqi(闰国棋),WANG Shudong(王树东),ZHANG Wenbiao(张文标).Research situation and development tendency of activated carbon from bamboo[J].Journal of Bamboo Research(竹子研究汇刊),2012,31(2):56-62.
- [11]State Environmental Protection Administration(国家环境保护总局).The monitor and analysis methods of air and exhaust gases(空气和废气监测分析方法)[M].Beijing:China Environmental Science Press,2003.