以内蒙古某矿区煤质为例煤中砷的赋存相关性分析Analysis of the correlated occurrence of arsenic in coal based on the mine samples from the mining area in Inner Mongolia
郑景华,刘天雪,刘志斌
摘要(Abstract):
采集内蒙古某矿区1#和2#井田主采煤层的煤样,分析煤样中的有机和无机组分,及煤中全硫和硫酸盐硫、硫化铁硫、有机硫三态的硫质量分数,并对煤样进行烧灼试验,测定了灰分中砷的质量比。运用SPSS软件,将煤中砷质量比与煤中有机和无机显微组分、全硫及三态硫质量分数分别进行一元回归分析。结果表明,煤中砷与有机显微组分中的半镜质组的相关系数为0.997,与无机显微组分黏土类、硫化物、碳酸盐的相关系数分别为0.998、1、0.981,呈正相关(p<0.05);煤中砷与全硫、硫化铁中硫和有机硫化物相关系数分别为0.986、0.979、0.991,呈显著正相关(p<0.001)。随着产灰率的增高,灰分中砷质量比也相应有增高趋势,二者存在显著线性关系。
关键词(KeyWords): 矿山安全;砷;赋存状态;回归分析
基金项目(Foundation): 国家自然科学基金项目(51174266)
作者(Author): 郑景华,刘天雪,刘志斌
参考文献(References):
- [1]BAI Xiangfei(白向飞),JIANG Ying(姜英).Arseniasis caused by coal combustion in China and prohibitive content of arsenic in commercial coals[J].Coal Quality Technology(煤质技术),2006(1):63-65.
- [2]ZHENG Liugen(郑刘根),LIU Guijian(刘桂建),GAO Lianfen(高连芬),et al.Arsenic in Chinese coals:its abundance,distribution,modes of occurrence,enrichment processes,and environmental significance[J].Acta Geoscientica Sinica(地球学报),2006,27(4):355-366.
- [3]LI Dahua(李大华),CHEN Kun(陈坤),DENG Tao(邓涛),et al.Content and correlation of arsenic in coal of southwestern China area[J].Coal Geology of China(中国煤田地质),2003,15(1):18-19.
- [4]WANG Mingshi(王明仕),ZHENG Baoshan(郑宝山),LIU Xiaojing(刘晓静),et al.Distribution of arsenic in southwest coals[J].Journal of China Coal Society(煤炭学报),2005,30(3):344-348.
- [5]WANG Mingshi(王明仕),ZHANG Xiao(张晓),YANG Nana(杨娜娜),et al.Research on arsenic content and its speciation distribution characteristics in overlying coal and fly ash recycling soil[J].Journal of Safety and Environment(安全与环境学报),2012,12(5):102-104.
- [6]ZHAO Fenghua(赵峰华),REN Deyi(任德贻),PENG Suping(彭苏萍),et al.The modes of occurrence of arsenic in coal[J].Advance in Earth Sciences(地球科学进展),2003,18(2):214-220.
- [7]WANG Wei(王餠),XU Xiaoyan(徐晓燕).Advances in study on arsenic adsorption on soil solid phases[J].Pollution Control Technology(污染防治技术),2008,21(6):60-64.
- [8]DING Z H,ZHENG B S,ZHUANG M,et al.Mode of occurrence of arsenic in high-As coals from endemic arsenosis areas in southwestern Guizhou Province,China[J].Journal of Coal Science&Engineering,2007,13(2):194-198.
- [9]CHEN Ping(陈萍),KUANG Hongwei(旷红伟),TANG Xiuyi(唐修义).Research on the distribution and occurrence of arsenic in coal[J].Journal of China Coal Society(煤炭学报),2002,27(3):259-263.
- [10]REN Hongyan(任红艳),ZHUANG Dafang(庄大方),QIU Dongsheng(邱冬生).Analysis of visible and near-infrared spectra of as-contaminated soil in croplands beside mines[J].Spectroscopy and Spectral Analysis(光谱学与光谱分析),2009,29(1):114-118.
- [11]FU Cong(傅丛),BAI Xiangfei(白向飞),JINAG Ying(姜英).Discussion on the relationship between the content of arsenic and the coal quality characteristic and the arsenic modes of occurrence in Chinese high arsenic coal[J].Journal of China Coal Society(煤炭学报),2012,37(1):96-102.
- [12]LU Xiaohua(陆晓华),ZENG Hancai(曾汉才),YAN Rong(晏蓉),et al.Modelling of the relationship between trace elements and three species of sulfur in coal[J].Environmental Chemistry(环境化学),1997,16(4):306-310.
- [13]ZHANG Zhenfu(张振桴),FAN Jinchuan(樊金串),JIN Jufang(晋菊芳),et al.Mode of occurrence of Pb,As,Be,Cr in coal[J].Journal of Fuel Chemistry and Technology(燃料化学学报),1992,20(2):206-211.
- [14]LIU Jing(刘晶),LU Xiaohua(陆晓华),GUO Xin(郭欣),et al.Speciation analysis of arsenic and mercury in coal[J].Journal of Huazhong University of Science and Technology(华中理工大学学报),2000,28(7):71-73.
- [15]TANG Lei(唐磊),YU Jiangping(虞江萍),JI Hongbing(季宏兵).The study on the mode of occurrence of arsenic in stone-coal of Shanxi[J].Journal of Capital Normal University:Natural Science Edition(首都师范大学学报:自然科学版),2008,29(5):85-88.
- [16]XIAO Liping(肖利萍),LIANG Bing(梁冰),LU Haijun(陆海军),et al.Analysis of characteristics of leaching release of some substances in coal gangue[J].Journal of Safety and Environment(安全与环境学报),2006,6(2):19-22.
- [17]TEIXEIM E C,DRTIZ L S,ALVES M F C C.et al.Distribution of selected heavy metals in fluvial sediments of the coal mining region[J].Environmental Geology,2001,41:145-151.