某垃圾焚烧飞灰理化性质检测及毒性浸出试验研究Physical and chemical properties detection and toxicity leaching experiment of a waste incineration fly ash
王博涛;董思涵;刘天成;
摘要(Abstract):
垃圾焚烧飞灰是危险废物,其资源化利用是环保产业的一项技术瓶颈。以实现垃圾焚烧飞灰的资源化为目的,通过理化性质检测和浸出毒性试验对飞灰进行分析。利用多功能粒径及粒形分析仪、X-射线粉末衍射仪、扫描电子显微镜和X-射线荧光光谱仪测定昆明某垃圾焚烧厂生活垃圾焚烧飞灰的理化性质,用电感耦合等离子体质谱方法分析飞灰的浸出毒性。结果表明,飞灰粒径分布集中在10~170μm,占比85.7%,D_(50)(中位粒径)为62.55μm。飞灰的主要成分是SiO_2、CaO、Fe_2O_3和Al_2O_3,其中SiO_2和CaO占飞灰总质量的58.7%,Fe_2O_3和Al_2O_3占总质量的17.9%。按照GB 5085.3—2007《危险废物鉴别标准浸出毒性鉴别》,飞灰浸出液中Pb、Zn、和Cd超标,浸出质量浓度分别是8.68 mg/L、130.5 mg/L和2.465 mg/L。研究结果可为飞灰提出新的资源化利用方式提供数据支撑。
关键词(KeyWords): 环境工程学;垃圾焚烧飞灰;理化性质;浸出毒性
基金项目(Foundation): 国家自然科学基金项目(51568068)
作者(Authors): 王博涛;董思涵;刘天成;
DOI: 10.13637/j.issn.1009-6094.2021.0237
参考文献(References):
- [1] 中华人民共和国国家统计局.中国统计年鉴[M].北京:中国统计出版社,2018.National Bureau of Statistics of the People's Republic of China.China Statistical Yearbook[M].Beijing:China Statistical Press,2018.
- [2] PHUA Z,GIANNIS A,DONG Z L,et al.Characteristics of incineration ash for sustainable treatment and reutilization[J].Environmental Science and Pollution Research,2019,26(17):16974-16997.
- [3] 刘杨,刘志英,徐学骁,等.垃圾焚烧飞灰制备水处理填料[J].环境污染与防治,2019,41(2):164-169.LIU Y,LIU Z Y,XU X X,et al.Preparation of water treatment fillers using municipal solid waste incineration fly ash[J].Environmental Pollution & Control,2019,41(2):164-169.
- [4] 赵倩倩.城市生活垃圾焚烧飞灰在资源化利用方面的综述[J].广东化工,2020,47(9):139-140.ZHAO Q Q.The overview of municipal solid waste incineration (MSWI) fly ash in resources utilization[J].Guangdong Chemical Industry,2020,47(9):139-140.
- [5] 黄庆,李惠,马东光,等.我国生活垃圾焚烧飞灰处置技术及相关政策总结[J].环境与发展,2020,32(8):243-244.HUANG Q,LI H,MA D G,et,al.Disposal technology of MSWI fly ash and relevant policy analysis in China[J].Environment and Development,2020,32(8):243-244.
- [6] 綦懿,李天如,王宝民,等.生活垃圾焚烧飞灰固化稳定化安全处置及建材资源化利用进展[J].建材技术与应用,2021(1):16-22.QI Y,LI T R,WANG B M,et al.Progress in solidification and stabilization of MSWI fly ash for safe disposal and resource utilization of building materials[J].Research and Application of Building Materials,2021(1):16-22.
- [7] 王俊,尹一林,李增和.垃圾燃烧飞灰合成材料对Pb2+的吸附[J].化工科技,2019,27(3):50-55.WANG J,YIN Y L,LI Z H.Removal of Pb2+ by waste incineration fly ash composite[J].Science&Technology in Chemical Industry,2019,27(3):50-55.
- [8] 李夫振,周少奇,林奕明.垃圾焚烧飞灰中不同粒径的毒性特性[J].环境工程学报,2013,7(2):684-688.LI F Z,ZHOU S Q,LIN Y M,et al.Toxicity characteristics of different particle sizes of fly ash from municipal solid waste incinerators[J].Jourmal of Evironmental Engineering,2013,7(12):684-688.
- [9] 庞俊峰,张建平,秦淼,等.生活垃圾焚烧飞灰处置及资源化利用研究[J].节能与环保,2020(10):84-85.PANG J F,ZHANG J P,QIN M,et al.Research on disposal and resource utilization of domestic waste incineration fly ash[J].Energy Conservation & Environmental Protection,2020(10):84-85.
- [10] 樊彦玲,郑鹏辉,祝文.垃圾焚烧飞灰无害化与资源化治理技术综述[J].资源节约与环保,2020(4):59.FAN Y L,ZHENG P H,ZHU W.Areview of harmless and resource recovery technologies for waste incineration fly ash[J].Resource Conservation and Environmental Protection,2020(4):59.
- [11] 罗任宏,李菁若,张东长,等.生活垃圾焚烧飞灰的资源化利用概况[J].环境影响评价,2019,41(4):63-66.LUO R H,LI J R,ZHANG D C,et al.General situation of municipal solid waste incineration fly ash resource utilization[J].Journal of Environmental Impact Assessment,2019,9(4):63-66.
- [12] 胡超超,王里奥,詹欣源,等.城市生活垃圾焚烧飞灰与电解锰渣烧制陶粒[J].环境工程学报,2019,13(1):177-185.HU C C,WANG L A,ZHAN X Y,et al.Preparation of ceramite with MSWI fly ash and electrolytic manganese residues[J].Chinese Journal of Environmental Engineering,2019,13(1):177-185.
- [13] ZENG C,YU Y,WANG D H,et al.Application of fly ash and slag generated by incineration of municipal solid waste in concrete[J].Advances in Materials Science and Engineering,2020(6):1-7.
- [14] 许鹏,赵庆良,邱微.垃圾焚烧飞灰制作碱激发砖的环境安全性评估[J].哈尔滨工业大学学报,2020,52(11):40-45.XU P,ZHAO Q L,QIU W.Environmental safety assessment of alkali-activated bricks produced by waste incineration fly ash[J].Journal of Harbin Institute of Technology,2020,52(11):40-45.
- [15] 颜可珍,郑凯高,胡迎斌.城市生活垃圾焚烧飞灰在沥青胶浆中的应用[J].铁道科学与工程学报,2018,15(10):2509-2517.YAN K Z,ZHENG K G,HU Y B.Application of municipalsolid waste incinerator ash in asphalt mortar[J].Journal of Railway Science and Engineering,2018,15(10):2509-2517.
- [16] 李保庆,郭艳平,党海峰.MgO对飞灰屏玻璃协同制备微晶玻璃析晶及性能的影响[J].矿产综合利用,2020(1):134-139.LI B Q,GUO Y P,DANG H F.Effect of MgO on crystallization and properties of glass ceramics from fly ash and waste glass[J].Multipurpose Utilization of Mineral Resources,2020(1):134-139.
- [17] 朱彧,吴昊,徐期勇.垃圾焚烧飞灰去除硫化氢气体[J].环境工程学报,2015,9(6):2947-2954.ZHU Y,WU H,XU Q Y.Removal of hydrogen sulfide by municipalsolid waste incineration fly ash[J].Chinese Journal of Environmental Engineering,2015,9(6):2947-2954.
- [18] 易龙生,刘涛,吴倩,等.生活垃圾焚烧飞灰-粉煤灰基多孔保温材料的制备[J].矿冶工程,2021,41(1):124-127.YI L S,LIU T,WU Q,et al.Preparation of porous thermal insultion material with MSWI fly ash and coal ash[J].Mining and Metallurgical Engineering,2021,41(1):124-127.
- [19] 刘坤,杨杉,邹家素,等.重庆市生态环保产业发展现状分析及对策建议[J].环境影响评价,2019,41(6):61-63,68.LIU K,YANG S,ZHOU J S,et al.Analysis and suggestions on development status of eco-environmental protection industry in Chongqing[J].Journal of Environmental Impact Assessment,2019,9(6):61-63,68.
- [20] 何品晶,吴长淋,章骅,等.生活垃圾焚烧飞灰及其稳定化产物的长期浸出行为[J].环境化学,2008(6):786-790.HE P J,WU C L,ZHANG H,et al.Long-term leaching behavior of fly ash from municipal solid waste incineration and its stabilized products[J].Environmental Chemistry,2008,27(6):786-790.
- [21] 叶暾旻,王伟,高兴保,等.我国垃圾焚烧飞灰性质及其重金属浸出特性分析[J].环境科学,2007(11):2646-2650.YE T M,WANG W,GAO X B,et al.Characterization and heavy metals leaching toxicity of fly ash from municipal solid waste incinerators in China[J].Environmental Science,2007(11):2646-2650.
- [22] 郭庶,谭海萍,黄俊明等.生活垃圾焚烧飞灰无害化处理后浸出液中危险成分最高容许浓度研究[J].安全与环境学报,2018,18(4):1478-1483.GUO S,TAN H P,HUANG J M,et al.Pursuit of the maximally allowable concentration of the toxic substances in MSWI fly ash leachates through harmless disposal[J].Journal of Safety and Environment,2018,18(4):1478-1483.
- [23] 国家环境保护总局.危险废物鉴别标准浸出毒性鉴别:GB 5085.3—2007[S].北京:中国标准出版社,2007.State Environmental Protection Administration of China.Identification standards for hazardous wastes identification for extraction toxicity:GB 5085.3—2007[S].Beijing:Standards Press of China,2007.
- [24] 李佳,张思奇,倪文,等.垃圾焚烧飞灰的固化及综合利用研究进展[J].金属矿山,2019(12):182-187.LI J,ZHANG S Q,NI W,et al.Research progress on solidification and comprehensive utilization of MSWI fly ash[J].Metal Mine,2019(12):182-187.
- [25] 罗建英,胡丹静,邵惠萍,等.城市垃圾焚烧飞灰物化特性动态分析[J].浙江化工,2019,50(7):41-46.LUO J Y,HU D J,SHAO H P,et al.Dynamic analysics on the physical and chemical characteristics of municipal waste incineration[J].Zhejiang Chemical Industry,2019,50(7):41-46.
- [26] MA W,CHEN D,PAN M,et al.Performance of chemical chelating agent stabilization and cement solidification on heavy metals in MSWI fly ash:a comparative study[J].Journal of Environmental Management,2019,247:169-177.
- [27] 李菁若,谭巍,张东长,等.沥青路用城市生活垃圾焚烧飞灰的物化性能[J].北京工业大学学报,2018,44(2):268-275.LI J R,TAN W,ZHANG D C,et al.Physical-chemical properties of municipal solid waste incinerator fly ash applied in asphalt pavement[J].Journal of Beijing University of Technology,2018,44(2):268-275.
- [28] DOMIMIC B V,CHAN W P,ZHENG H P,et al.The use of fly ashes from waste-to-energy processes as mineral CO2 sequesters and supplementary cementitious materials[J].Journal of Hazardous Materials,2020,398:122906.
- [29] 伍灵梅,任旭.掺生活垃圾焚烧飞灰的水泥稳定碎石性能研究[J].山东交通科技,2020(1):41-43,55.WU L M,REN X.Effects of domestic waste incineration fly ash on the characterization of cement stabilized macadam[J].Shandong Communications Technology,2020(1):41-43,55.
- [30] LIU J,HU L,TANG L P,et al.Utilisation of municipal solid waste incinerator (MSWI) fly ash with metakaolin for preparation of alkali-activated cementitious material[J].Journal of Hazardous Materials,2020,402(4):123451.
- [31] JIANG J G,XU X,WANG J,et al.Investigation of basic properties of fly ash from urban waste incinerators in China[J].Journal of Environmental Sciences,2007,19(4):458-463.
- [32] BAYUSENO A P,SCHMAHL W W,MüLLEJANS T H.Hydrothermal processing of MSWI fly ash-towards new stable minerals and fixation of heavy metals[J].Journal of Hazardous Materials,2008,167(1):250-259.
- [33] 蒋旭光,陈钱,赵晓利,等.水热法稳定垃圾焚烧飞灰中重金属研究进展[J].化工进展,2021,40(8):4473-4485.JIANG X G,CHEN Q,ZHAO X L,et al.A review on hydrothermal treatment for stabilization of heavy metals in fly ash from municipal solid waste incineration[J].Chemical Industry and Engineering Progress,2021,40(8):4473-4485.
- [34] 阮煜,宗达,陈志良,等.水热法协同处置不同垃圾焚烧炉飞灰及其机理[J].中国环境科学,2018,38(7):2602-2608.RUAN Y,ZONG D,CHEN Z L,et al.Co-hydrothermal processing for stabilize of different waste incinerator fly ash and its mechanism[J].China Environmental Science,2018,38(7):2602-2608.
- [35] 周珍雄,邵倩,余姮蓉,等.垃圾焚烧飞灰水洗脱氯资源化研究[J].广东化工,2021,48(6):106-107,116.ZHOU Z X,SHAO Q,YU H R,et al.The study of fly ash resources from domestic garbage incineration by water washing[J].Guangdong Chemical Industry,2021,48(6):106-107,116.
- [36] WANG X X,ZHANG L,ZHU K Y,et al.Distribution and chemical species transition behavior of chlorides in municipal solid waste incineration fly ash during the pressure-assisted sintering treatment[J].Chemical Engineering Journal,2021,415:128873.
- [37] 环境保护部.水泥窑协同处置固体废物环境保护技术规范:HJ 662—2013[S].北京:中国环境科学出版社,2003.Ministry of Environmental Protection.Environmental protection technical specification for co-processing ofsolid wastes in cement kiln:HJ 662—2013[S].Beijing:Sciences Press of China,2013.
- [38] 中华人民共和国国家质量监督检验检疫总局.通用硅酸盐水泥:GB 175—2007[S].北京:中国标准出版社,2007.General Administration of Quality Supervision,Inspection and Quarantine of the People's Republic of China.Common portland cement:GB 175—2007[S].Beijing:Standards Press of China,2007.
- [39] 苏博文,史公初,廖亚龙,等.工业固体废弃物制备二氧化硅功能材料的研究进展[J].材料导报,2021,35(3):3026-3032.SU B W,SHI G C,LIAO Y L,et al.Research progress on functional materials preparation of silica from industrial solid wastes[J].Materials Reports,2021,35(3):3026-3032.
- [40] LI C Q,LIANG C,CHEN Z M,et al.Surface modification of calcium carbonate:a review of theories,methods and applications[J].Journal of Central South University:2021,28(9):2589-2611.
- [41] ZHU J M,HAO Q J,CHEN JJ,et al.Distribution characteristics and comparison of chemical stabilization ways of heavy metals from MSW incineration fly ashes[J].Waste Management,2020,113:488-496.
- [42] 宋倩楠,王峰,童立志,等.药剂螯合对飞灰重金属形态及浸出行为的影响[J].应用化工,2021,50(3):571-576.SONG Q N,WANG F,TONG L Z,et al.Effect of chelating agents on forms and leaching behavior of heavy metals in fly ash[J].Applied Chemical Industry,2021,50(3):571-576.
- [43] TAKASHI F,YUTA T,MASAKI T.Coexistence of Cu,Fe,Pb,and Zn oxides and chlorides as a determinant of chlorinated aromatics generation in municipal solid waste incinerator fly ash[J].Environmental Science & Technology,2014,48(1):85-92.
- [44] YU M J,TIAN S L,CHU W S,et al.Speciation of zinc in secondary fly ashes of municipal solid waste at high temperatures[J].Journal of Synchrotron Radiation,2009,16(4):528-532.
- [45] 郝志鹏,范新秀,陈璐,等.螯合剂稳定化飞灰中Pb和Cd浸出行为研究[J].环境污染与防治,2018,40(6):667-671.HAO Z P,FAN X X,CHEN L,et al.Study on leaching behavior of Pb and Cd in chelating stabilized fly ash[J].Environmental Pollution & Control,2018,40(6):667-671.
- [46] 刘忠,王硕,白宝泉.燃煤飞灰中矿物质对烟气中As、Se、Pb形态分布影响的热力学研究[J].燃料化学学报,2020,48(12):1530-1536.LIU Z,WANG S,BAI B Q.Thermodynamic study on effect of minerals in fly ash on morphological distribution of As,Se and Pb in flue gas[J].Journal of Fuel Chemistry and Technology,2020,48(12):1530-1536.