掺氮碳纳米管的制备及其锂硫电池性能Synthesis and electrochemical behavior of nitrogen doped carbon nano-tubes for lithium sulfur batteries
李寅川,梅军
摘要(Abstract):
采用化学气相沉积的方法合成了掺氮碳纳米管(N-CNTs)。相较于纯碳纳米管(CNTs),N-CNTs拥有更多结构上的缺陷,具有更高的导电性能,且硫在其表面的分布更加均匀,从而提升了掺氮碳纳米管/硫(N-CNTs/S)复合材料的性能。与纯碳纳米管/硫(CNTs/S)电极相比,N-CNTs/S电极在不同倍率下首放电比容量提升了近30%,在837.5 mA/g的电流密度下循环100圈后,放电容量的保持能力也更好。这表明氮掺杂提升了锂硫电池正极材料的电化学性能。
关键词(KeyWords): 储能技术;碳纳米管;氮掺杂;锂硫电池
基金项目(Foundation):
作者(Author): 李寅川,梅军
参考文献(References):
- [1]SCROSATI B,GARCHE J.Lithium batteries:status,prospects and future[J].Journal of Power Sources,2010,195:2419-2430.
- [2]TARASCON J M,ARMAND M.Issues and challenges facing rechargeable lithium batteries[J].Nature,2001,414:359-367.
- [3]XIE Man(谢嫚),DENG Jinxun(邓锦勋),WU Feng(吴锋).Property of composite polymer electrolyte for lithium ion battery[J].Journal of Safety and Environment(安全与环境学报),2004,4(6):48-50.
- [4]JACOBSON M Z.Review of solutions to global warming,air pollution,and energy security[J].Energy&Environmental Science,2009,2:148-173.
- [5]BRUCE P G,FREUNBERGER S A,HARDWICK L J,et al.Li-O2and Li-S batteries with high energy storage[J].Nature Materials,2012,11:19-29.
- [6]MANTHIRAM A,FU Y,SU Y S.Challenges and prospects of lithium-sulfur batteries[J].Accounts of Chemical Research,2013,46:1125-1134.
- [7]BARCHASZ C,LEPRETRE J C,ALLOIN F,et al.New insights into limiting parameters of the Li/S rechargeable cell[J].Journal of Power Sources,2012,199:322-330.
- [8]YANG Yuan,ZHENG Guangyuan,CUI Yi.Nanostructured sulfur cathodes[J].Chemical Society Reviews,2013,42:3018-3032.
- [9]JAYAPRAKASH N,SHEN J,MOGANTY S S,et al.Porous hollow carbon@sulfur composites for high-power lithium-sulfur batteries[J].Angewandte Chemie International Edition,2011,50:5904-5908.
- [10]SEH Z,LI W,CHA J,et al.Sulphur-TiO2yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries[J].Nature Communications,2013,4:1331-1336.
- [11]ZHENG Guangyuan,YANG Yuan,CHA J J,et al.Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries[J].Nano Letters,2011,11:4462-4467.
- [12]JI Liwen,RAO Mumin,ALONI S,et al.Porous carbon nanofibersulfur composite electrodes for lithium/sulfur cells[J].Energy&Environmental Science,2011,4:5053-5059.
- [13]LU Songtao,CHENG Yingwen,WU Xiaohong,et al.Significantly improved long-cycle stability in high-rate Li-S batteries enabled by coaxial graphene wrapping over sulfur coated carbon nanofibers[J].Nano Letters,2013,13:2485-2489.
- [14]JI Xiulei,LEE K T,NAZAR L F.A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphurbatteries[J].Nature Materials,2009,8:500-506.
- [15]GUO Juchen,XU Yunhua,WANG Chunsheng.Sulfur-impregnated disordered carbon nanotubes cathode for lithium-sulfur batteries[J].Nano Letters,2011,11:4288-4294.
- [16]LIANG Xiao,WEN Zhaoyin,LIU Yu,et al.A composite of sulfur and polpyrrole-multi walled carbon combinatorial nanotubes as cathode for Li/S battery[J].Journal of Power Sources,2012,206:409-413.
- [17]WEI Wei,WANG Jiulin,ZHOU Longjie,et al.CNT enhanced sulfur composite cathode material for high rate lithium battery[J].Electrochemistry Communications,2011,13:399-402.
- [18]ZHENG W,LIU Y W,HU X G,et al.Novel nanosized adsorbing sulfur composite cathode materials for the advanced secondary lithium batteries[J].Electrochimica Acta,2006,51:1330-1335.
- [19]AHN W,KIM K B,JUNG K N,et al.Synthesis and electrochemical properties of a sulfur-multi walled carbon nanotubes composite as a cathode material for lithium sulfur batteries[J].Journal of Power Sources,2012,202:394-399.
- [20]PATTINSON S W,DIAZ R E,STELMASHENKO N A,et al.In situ observation of the effect of nitrogen on carbon nanotube synthesis[J].Chemistry of Materials,2013,25:2921-2923.
- [21]WIGGINS-CAMACHO J D,STEVENSON K J.Effect of nitrogen concentration on capacitance,density of states,electronic conductivity,and morphology of N-doped carbon nanotube electrodes[J].Journal of Physical Chemistry C,2009,113:19082-19090.
- [22]NXUMALO E N,NYAMORI V O,COVILLE N J.CVD synthesis of nitrogen doped carbon nanotubes using ferrocene/aniline mixtures[J].Journal of Organometallic Chemistry,2008,693:2942-2948.
- [23]REN Wei,LI Dejun,LIU Hao,et al.Lithium storage performance of carbon nanotubes with different nitrogen contents as anodes in lithium ions batteries[J].Electrochimica Acta,2013,105:75-82.
- [24]SUN X G,WANG X,MAYES R T,et al.Lithium-sulfur batteries based on nitrogen-doped carbon and an lonic-liquid electrolyte[J].ChemSusChem,2012,5:2079-2085.
- [25]LIU Hao,ZHANG Yong,LI Ruying,et al.Structural and morphological control of aligned nitrogen-doped carbon nanotubes[J].Carbon,2010,48:1498-1507.
- [26]CHEN Yougui,WANG Jiajun,LIU Hao,et al.Enhanced stability of Pt electrocatalysts by nitrogen doping in CNTs for PEM fuel cells[J].Electrochemistry Communications,2009,11:2071-2076.
- [27]GHOSH K,KUMAR M,MARUYAMA T,et al.Tailoring the field emission property of nitrogen-doped carbon nanotubes by controlling the graphitic/pyridinic substitution[J].Carbon,2010,48:191-200.
- [28]KIM S Y,LEE J,NA C W,et al.N-doped double-walled carbon nanotubes synthesized by chemical vapor deposition[J].Chemical Physics Letters,2005,413:300-305.
- [29]JI Liwen,RAO Mumin,ZHENG Haimei,et al.Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells[J].Journal of the American Chemical Society,2011,133:18522-18525.
- [30]ZU Chenxi,MANTHIRAM A.Hydroxylated graphene-sulfur nanocomposites for high-rate lithium-sulfur batteries[J].Advanced Functional Materials,2013,3:1008-1012.
- [31]CHUANG C C,HUANG J H,CHEN W J,et al.Role of amorphous carbon nanowires in reducing the turn-on field of carbon films prepared by microwave-heated CVD[J].Diamond and Related Materials,2004,13:1012-1016.
- [32]ZHANG S S,XU K,JOW T R.The low temperature performance of Li-ion batteries[J].Journal of Power Sources,2003,115:137-140.
- [33]SUN Xiaoguang,ANGELL C A.Doped sulfone electrolytes for high voltage Li-ion cell applications[J].Electrochemistry Communications,2009,11:1418-1421.