不同风化程度煤的结构与生物产气效果的变化特征Variation characteristics of the structure and biological gas production effect of coal with different weathering degrees
郭红玉;李赛赛;沈野;李云嵩;许小凯;刘小磊;
摘要(Abstract):
为探究风化煤的结构与生物产气效果的变化特征,拓宽风化煤的利用途径,选取内蒙古乌海、山西晋城和太原西山不同风化程度的煤样,以矿井水为菌种来源进行生物产气模拟试验,并从煤的显微组分与官能团方面解释生物产气效果。结果表明:随风化程度加深,煤样镜质组边界与裂隙周围存在的氧化边缘越来越明显,裂隙增大,脂碳、芳碳和羰基的分峰占比下降,芳香结构被破坏,羧基的分峰占比明显增加,含氧官能团的分峰占比整体提升,羧基的分峰占比增加会使产气总量明显增加;煤样受到严重风化后,即使其生物产气总量继续增加,但CH_4体积分数可能会出现下降趋势。
关键词(KeyWords): 环境工程学;风化煤;显微组分;官能团;生物产气
基金项目(Foundation): 国家自然科学基金项目(41972178,42072193);; 河南省优秀青年科学基金项目(202300410168)
作者(Authors): 郭红玉;李赛赛;沈野;李云嵩;许小凯;刘小磊;
DOI: 10.13637/j.issn.1009-6094.2021.0556
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