纳米铁活化过硫酸盐与超滤组合对二级出水中污染物的去除效能及影响因素Removal of pollutants in the secondary effluent by nano-iron activated persulfate and ultrafiltration combined process and its influencing factors
孙丽华;梅筱禹;高呈;冯萃敏;
摘要(Abstract):
针对污水处理厂二级出水开展深度处理研究,采用纳米铁(nFe)活化过硫酸盐(PS)-超滤(UF)组合工艺去除二级出水中抗生素抗性基因(ARGs)和有机物,并探究pH值和温度对ARGs去除率的影响。结果表明,与直接UF和PS-UF工艺相比,nFe/PS-UF组合工艺对二级出水中ARGs、int I1及16S rRNA的去除效果最佳,对数削减量为2.51~3.52;二级出水中游离态ARGs比细胞态ARGs含量高,nFe/PS-UF组合工艺对细胞态和游离态ARGs去除效果优于直接UF和PS-UF组合工艺,其对细胞态和游离态ARGs的对数削减量分别为2.91~3.82和2.35~3.42;组合工艺对溶解性有机碳(DOC)和不同类型有机物的去除效果最好。其中DOC的去除率为30.0%,酪氨酸类、色氨酸类、富里酸类和腐殖酸类有机物去除率分别为84.5%、81.3%、81.1%和45.5%,且水中DOC含量与不同种类ARGs浓度有显著相关性。pH值和温度对组合工艺去除二级出水中ARGs有显著影响,pH值降低和温度升高有利于提高组合工艺对ARGs的去除效果。
关键词(KeyWords): 环境工程学;抗性基因;过硫酸盐;纳米铁;超滤;自由基
基金项目(Foundation): 国家自然科学基金项目(52070011)
作者(Authors): 孙丽华;梅筱禹;高呈;冯萃敏;
DOI: 10.13637/j.issn.1009-6094.2021.0174
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