气象条件对夏秋季炼油厂附近臭氧及其前体物的影响Meteorological effects on the ozone and its precursors variations around the oil-refinery in summer and autumn
李国昊,魏巍,程水源,王海燕,王刚
摘要(Abstract):
在夏秋季对我国北方某石化炼油厂附近大气中的O3及其前体物的体积分数进行了监测,分析了其日变化特征及其与气象要素的相关性,并分析了O3超标与未超标期间气象条件与O3前体物的特征。结果表明,夏秋季炼油厂附近O3体积分数超标严重。O3体积分数呈单峰型日变化,在午后15:00左右出现日最大值,夜晚体积分数较低;而NOx和VOCs体积分数与O3相反,白天较低,夜间较高,并呈现双峰型日变化。烯烃和苯系物体积百分比的日变化趋势为先降低后升高,烷烃体积百分比的日变化趋势则相反。夏秋季O3体积分数变化与温度、风速成正相关,与相对湿度成负相关。O3超标与未超标期间前体物体积分数及气象条件均存在显著差异,温度、相对湿度在O3超标期间均大于未超标期间,风速则相反。NO和VOCs体积分数在O3超标期间均小于未超标期间,而NO2体积分数差别不大。在O3体积分数最大的午后14:00,烯烃和苯系物体积百分比在O3超标期间小于未超标期间。
关键词(KeyWords): 环境学;炼油厂;臭氧;VOCs;气象条件
基金项目(Foundation): 环保公益性行业科研专项(201209003)
作者(Author): 李国昊,魏巍,程水源,王海燕,王刚
参考文献(References):
- [1]RADDATZ R L,CUMMINE J D.Temporal surface ozone patterns in urban Manitoba,Canada[J].Bounday-Layer Meteorology,2001,99:411-428.
- [2]DUENAS C,FERNANDEZ M C,CANETE S,et al.Assessment of ozone variations and meteorological effects in an urban area in the Mediterranean coast[J].Science of the Total Environment,2002,299:97-113.
- [3]LEHMAN J,SWINTON K,BORTNICK S,et al.Spatio-temporal characterization of tropospheric ozone across the eastern United States[J].Atmospheric Environment,2004,38:4357-4369.
- [4]SHAO Min(邵敏),ZHAO Meiping(赵美萍),BAI Yuhua(白郁华),et al.A study of NMHC character in atmosphere of YANSHAN petrochemical region[J].Environmental Chemistry(环境化学),1994,13(1):40-45.
- [5]CHEN C L,SHU C M,FANG H Y.Location and characterization of emission sources for airborne volatile organic compounds inside a refinery in Taiwan[J].Environmental Monitoring and Assessment,2006,120:487-498.
- [6]SUN Xiaoqiang(孙筱强),CHENG Shuiyuan(程水源),WEI Wei(魏巍),et al.Refinery O3variation characteristics and VOCs reactivity research[J].Journal of Safety and Environment(安全与环境学报),2011,11(6):101-105.
- [7]CETIN E,ODABASI M,SEYFIOGLU R.Ambient volatile organic compound(VOC)concentrations around a petrochemical complex and a petroleum refinery[J].Science of the Total Environment,2003,312:103-112.
- [8]SATSANGI G S,LAKHANI A,KULSHRESTHA P R,et al.Seasonal and diurnal variation of surface ozone and a preliminary analysis of exceedance of its critical levels at a semi-arid site in India[J].Journal of Atmospheric Chemistry,2004,47:271-286.
- [9]ELMINIR H K.Dependence of urban air pollutants on meteorology[J].Science of the Total Environment,2005,350:225-237.
- [10]AN Junlin(安俊琳),WANG Yuesi(王跃思),SUN Yang(孙扬).Assessment of ozone variations and meteorological effects in Beijing[J].Ecology and Environmental Sciences,2009,18(3):944-951.
- [11]GB 3095—2012 Ambient air quality standards(环境空气质量标准)[S].