| 50 | 0 | 77 |
| 下载次数 | 被引频次 | 阅读次数 |
注浆是破碎围岩稳定性控制的重要技术手段,为填补传统水泥基注浆材料脆性大、变形适应差、易开裂失效的缺陷,引入改性稻壳纤维(Rice Husk Fiber,RHF)制备新型增韧水泥基注浆材料。通过开展浆液流动性测试和结石体无侧限抗压强度、抗折强度等试验,分析RHF掺入对水泥基注浆材料工程特性的影响,确定最优掺量,并结合傅里叶红外光谱与扫描电子显微镜等微观表征手段,探究RHF的增韧机理。结果表明:随RHF掺量增加,浆液流动度、析水率和抗压强度逐渐下降,初凝与终凝时间延长,抗折强度呈先增后减趋势;试样轴向应变增大,峰后残余强度提高,压缩破坏由脆性劈裂破坏向延性破坏转变,弯曲断裂裂缝由脆性弯曲裂缝演化为延性弯剪裂缝,材料变形协调能力增强。RHF掺量为3‰时,材料韧性最优。RHF与水泥基体结合紧密,在裂缝扩展过程中发挥桥接、拔出及断裂耗能作用,抑制裂缝发展,提高材料变形与吸能能力,实现水泥基注浆材料韧性提升。
Abstract:Grouting is a vital technique for controlling the stability of fractured surrounding rock. To address the limitations of traditional cement-based grouting materials—such as high brittleness, poor deformation adaptability, and susceptibility to cracking and failure—a novel toughened cement-based grouting material has been developed by incorporating modified Rice Husk Fiber (RHF), which underwent treatment through crushing, acid boiling, alkali soaking, and surface coating. We conducted slurry fluidity tests and experiments on the unconfined compressive strength, flexural strength, and static elastic modulus of the hardened specimens to determine the slurry’s setting time, flowability, and bleeding rate. By analyzing the stress-strain curves and failure modes of the samples, we investigated the influence and toughening effect of RHF incorporation on the engineering properties of cement-based grouting materials to identify the optimal fiber content. Furthermore, microstructural characterization techniques such as Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) were employed to elucidate the toughening mechanism of RHF within the cement matrix. The results indicate that: (1) As RHF content increases, the slurry's flowability, bleeding rate, and compressive strength gradually decrease, while the initial and final setting times are prolonged. The flexural strength initially increases before decreasing. Notably, the axial strain of the specimens rises, post-peak residual strength improves, the compressive failure mode transitions from columnar brittle splitting to ductile shear failure, and flexural cracks evolve from brittle bending cracks to ductile bending–shear cracks, demonstrating enhanced deformation compatibility of the material. The optimum toughness is achieved at an RHF content of 3‰. (2) RHF forms an effective bond with the cement matrix through interfacial friction, adhesion, and interlocking effects, providing bridging, pull-out, and fracture resistance. This inhibits crack development, enhances the deformation capacity and energy absorption characteristics of the material, and leads to improved toughness in cement-based grouting materials. These research findings provide a scientific basis for optimizing grouting reinforcement materials for fractured surrounding rock and ensuring engineering safety.
[1] 张进鹏, 刘立民, 刘传孝, 等. 深部裂隙岩体硅质自应力注浆加固机制与试验[J]. 煤炭学报, 2020, 45(增刊2): 755–765.
[2] Wang Xin, Li Lianchong, Mu Wenqiang, et al. Diffusion mechanism of cement-based slurry in frozen and thawed fractured rock mass in alpine region[J]. Construction and Building Materials, 2024, 411: 134584.
[3] Li Zhan, Liu Huoxing, Dun Zhilin, et al. Grouting effect on rock fracture using shear and seepage assessment[J]. Construction and Building Materials, 2020, 242: 118131.
[4] Wang Yuke, Zhang Liao, Liu Mengcheng, et al. Comparative study on the mechanical properties of solidified silty-fine sand reinforced by permeable polymer and traditional grouting materials[J]. Construction and Building Materials, 2024, 419: 135485.
[5] 刘凤文, 蓝盛, 张盛. 钱家营煤矿巷道掘进瓦斯突出治理及冒落区超前锚注修复技术[J]. 安全与环境学报, 2019, 19(4): 1154–1161.
[6] 张海波, 狄红丰, 刘庆波, 等. 微纳米无机注浆材料研发与应用[J]. 煤炭学报, 2020, 45(3): 949–955.
[7] 管学茂, 张海波, 杨政鹏, 等. 高性能无机–有机复合注浆材料研究[J]. 煤炭学报, 2020, 45(3): 902–910.
[8] 严国超, 白龙剑, 张志强, 等. PU改性硫铝酸盐水泥注浆材料试验与应用[J]. 煤炭学报, 2020, 45(增刊2): 747–754.
[9] 李浩, 梁卫国, 李国富, 等. 碎软煤层韧性破坏–渗流耦合本构关系及其间接压裂工程验证[J]. 煤炭学报, 2021, 46(3): 924–936.
[10] Ohama Y. Study on properties and mix proportioning of polymer-modified mortars for buildings[J]. Report of the Building Research Institute, 1973, 65: 100–104.
[11] Zhang Haibo, Zhou Rong, Liu Songhui, et al. Enhanced toughness of ultra-fine sulphoaluminate cement-based hybrid grouting materials by incorporating in-situ polymerization of acrylamide[J]. Construction and Building Materials, 2021, 292: 123421.
[12] 郭鑫, 李大芳, 鲁义, 等. GO–PVA注浆材料的制备及其强度特征研究[J]. 安全与环境学报, 2024, 24(10): 3827–3838.
[13] Mohammed A, Mahmood W, Ghafor K. TGA, rheological properties with maximum shear stress and compressive strength of cement-based grout modified with polycarboxylate polymers[J]. Construction and Building Materials, 2020, 235: 117534.
[14] Chhun K T, Lee S H, Keo S A, et al. Effect of acrylate-cement grout on the unconfined compressive strength of silty sand[J]. KSCE Journal of Civil Engineering, 2019, 23(6): 2495–2502.
[15] 胡浩聪, 刘娟红, 王金安. 纤维增强混凝土韧性及声发射特征分析[J]. 煤炭学报, 2023, 48(3): 1209–1219.
[16] 郑山锁, 李浩冲, 阮升, 等. 掺稻壳灰与纤维素纤维混凝土抗氯离子渗透和抗冻性试验研究[J]. 湖南大学学报(自然科学版), 2024, 51(5): 193–206.
[17] 徐维生, 张驰, 李丽华, 等. 稻壳纤维加筋水泥土强度试验及估测模型研究[J/OL]. 武汉大学学报(工学版): 1–11[2026–02–24]. https://link.cnki.net/urlid/42.1675.T.20231010.1507.002.
[18] 赵丽, 李书进, 宋杨, 等. 植物纤维增强水泥基复合材料研究进展[J]. 建筑材料学报, 2022, 25(10): 1021–1026.
[19] Choi Y C. Hydration and internal curing properties of plant-based natural fiber-reinforced cement composites[J]. Case Studies in Construction Materials, 2022, 17: e01690.
[20] Yan Jie, Yang Bo, Feng Longhui, et al. Effect of modified jute fibre on mechanical and microstructural properties of recycled aggregate concrete[J]. Construction and Building Materials, 2025, 492: 143008.
[21] 张建俊, 姚柏聪, 孙源骏, 等. 离子固化剂对水泥稳定煤矸石结合料耐久性能的影响[J]. 煤炭学报, 2022, 47(9): 3472–3482.
[22] GB/T 8077—2023 混凝土外加剂匀质性试验方法[S].
[23] GB/T 50080—2016 普通混凝土拌合物性能试验方法标准[S].
[24] GB/T 1346—2024 水泥标准稠度用水量、凝结时间与安定性检验方法[S].
[25] GB/T 17671—2021 水泥胶砂强度检验方法(ISO法)[S].
[26] Dong Kai, Ni Guanhua, Nie Baisheng, et al. Effect of polyvinyl alcohol/aluminum microcapsule expansion agent on porosity and strength of cement-based drilling sealing material[J]. Energy, 2021, 224: 119966.
[27] 席歆玥, 张延生, 杨云波, 等. 绿筑智建: 农业生物质纤维强化再生水泥3D打印绿色建材研究[J/OL]. 材料导报: 1–18[2026–01–10]. https://link.cnki.net/urlid/50.1078.TB.20250612.1331.016.
[28] Han Yi, Shi Mingxin, Lee S, et al. Application of porous luffa fiber as a natural internal curing material in high-strength mortar[J]. Construction and Building Materials, 2024, 455: 139169.
[29] Sharma V, Vinayak H K, Marwaha B M. Enhancing compressive strength of soil using natural fibers[J]. Construction and Building Materials, 2015, 93: 943–949.
[30] Mahdi S N, Hossiney N, Abdullah M M A B. Strength and durability properties of geopolymer paver blocks made with fly ash and brick kiln rice husk ash[J]. Case Studies in Construction Materials, 2022, 16: e00800.
[31] Abadel A, Abbas H, Almusallam T, et al. Discussion: Mechanical properties of hybrid fibre-reinforced concrete–analytical modelling and experimental behaviour[J]. Magazine of Concrete Research, 2016, 68(22): 1183–1186.
[32] Boulekbache B, Hamrat M, Chemrouk M, et al. Failure mechanism of fibre reinforced concrete under splitting test using digital image correlation[J]. Materials and structures, 2015, 48(8): 2713–2726.
[33] 刘永毅, 任尊超, 袁连旺, 等. 响应曲面法优化高强硅酸盐水泥熟料矿物组成的研究[J]. 硅酸盐通报, 2021, 40(4): 1088–1096.
[34] Tam L, Moundi A, Jing Guoqing, et al. Molecular investigation on interfacial toughening between silane coupling agent treated glass fiber and cement[J]. Journal of Building Engineering, 2024, 95: 110218.
[35] Fernando A, Selvaranjan K, Srikanth G, et al. Development of high strength recycled aggregate concrete-composite effects of fly ash, silica fume and rice husk ash as pozzolans[J]. Materials and Structures, 2022, 55(7): 185.
基本信息:
DOI:10.13637/j.issn.1009-6094.2025.1805
中图分类号:TU578
引用信息:
[1]张建俊,韩健,孙闯,等.改性稻壳纤维增韧水泥基注浆材料工程特性试验研究[J].安全与环境学报().DOI:10.13637/j.issn.1009-6094.2025.1805.
基金信息:
辽宁省重点项目(JYTZD2023077)
2026-08-07
2026-08-07
2026-08-07